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P h ö t ö g r ä p h y is feeling blessed at Chandigarh University January 30, · Like Comment Share V ï s h ú P h ö t ö g r ä p h y August 31, 19 · Today's clickC Z ֡ h3چ 4 o Wp C z = v Y 4 1/ 9c 7 G ȅA S ES PHh8 P N 5 V i 4 ^ p(= m f Ax * C( F h & h/@ V 8;Ag ?Ѩ ҄6 m 1 ˃ 8 X M > endobj 10 0 obj >stream hHeat from system to bath should be ( U/ V) since vacuum p ext = 0, w = 0, so dU = dq = dU V dU T Joule result no change in T, so assume dT sys = dT sur = 0 or dq = 0 ( U/ V) T dV = 0 since dV ≠ 0 ( U/ V) T = 0 Joule experiment not sensitive enough, but observation does fit
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V = velocity of atom/molecule, m = mass of each molecule (all molecules are identical in kinetic theory), γ(p) = Lorentz factor as function of momentum (see below) Ratio of thermal to rest massenergy of each molecule = /It may be noted that Gibb's function g = (h – Ts) is a property of the system where availability function a = (u p 0 v – T 0 s) is a composite property of the system and surroundings Again, a = u p 0 v – T 0 s b = u pv – T 0 s g = u pv – Ts When state 1 proceeds to dead state (zero state) a = b = gTo derive the relationships between the various thermodynamic variables, rst take s and V as independent, and rewrite (18) as du = Tds P dV (19) However, when written in terms of s and V, du is formally du = @u @s) V ds @u @V) s dV which means that
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